29 Introduction to Quantum Physics

# 236 29.7 Probability: The Heisenberg Uncertainty Principle

Probability: The Heisenberg Uncertainty Principle
• Use both versions of Heisenberg’s uncertainty principle in calculations.
• Explain the implications of Heisenberg’s uncertainty principle for measurements.

# Probability Distribution

Matter and photons are waves, implying they are spread out over some distance. What is the position of a particle, such as an electron? Is it at the center of the wave? The answer lies in how you measure the position of an electron. Experiments show that you will find the electron at some definite location, unlike a wave. But if you set up exactly the same situation and measure it again, you will find the electron in a different location, often far outside any experimental uncertainty in your measurement. Repeated measurements will display a statistical distribution of locations that appears wavelike. (See [link].)

After de Broglie proposed the wave nature of matter, many physicists, including Schrödinger and Heisenberg, explored the consequences. The idea quickly emerged that, because of its wave character, a particle’s trajectory and destination cannot be precisely predicted for each particle individually. However, each particle goes to a definite place (as illustrated in [link]). After compiling enough data, you get a distribution related to the particle’s wavelength and diffraction pattern. There is a certain probability of finding the particle at a given location, and the overall pattern is called a probability distribution. Those who developed quantum mechanics devised equations that predicted the probability distribution in various circumstances.

It is somewhat disquieting to think that you cannot predict exactly where an individual particle will go, or even follow it to its destination. Let us explore what happens if we try to follow a particle. Consider the double-slit patterns obtained for electrons and photons in [link]. First, we note that these patterns are identical, following dsinθ=mλdsinθ=mλ size 12{d”sin”θ=mλ} {}, the equation for double-slit constructive interference developed in Photon Energies and the Electromagnetic Spectrum, where dd size 12{d} {} is the slit separation and λλ size 12{λ} {} is the electron or photon wavelength.

Both patterns build up statistically as individual particles fall on the detector. This can be observed for photons or electrons—for now, let us concentrate on electrons. You might imagine that the electrons are interfering with one another as any waves do. To test this, you can lower the intensity until there is never more than one electron between the slits and the screen. The same interference pattern builds up! This implies that a particle’s probability distribution spans both slits, and the particles actually interfere with themselves. Does this also mean that the electron goes through both slits? An electron is a basic unit of matter that is not divisible. But it is a fair question, and so we should look to see if the electron traverses one slit or the other, or both. One possibility is to have coils around the slits that detect charges moving through them. What is observed is that an electron always goes through one slit or the other; it does not split to go through both. But there is a catch. If you determine that the electron went through one of the slits, you no longer get a double slit pattern—instead, you get single slit interference. There is no escape by using another method of determining which slit the electron went through. Knowing the particle went through one slit forces a single-slit pattern. If you do not observe which slit the electron goes through, you obtain a double-slit pattern.

# Heisenberg Uncertainty

How does knowing which slit the electron passed through change the pattern? The answer is fundamentally important—measurement affects the system being observed. Information can be lost, and in some cases it is impossible to measure two physical quantities simultaneously to exact precision. For example, you can measure the position of a moving electron by scattering light or other electrons from it. Those probes have momentum themselves, and by scattering from the electron, they change its momentum in a manner that loses information. There is a limit to absolute knowledge, even in principle.

It was Werner Heisenberg who first stated this limit to knowledge in 1929 as a result of his work on quantum mechanics and the wave characteristics of all particles. (See [link]). Specifically, consider simultaneously measuring the position and momentum of an electron (it could be any particle). There is an uncertainty in position ΔxΔx size 12{Δx} {} that is approximately equal to the wavelength of the particle. That is,

Δx≈λ.Δx≈λ. size 12{Δx approx λ} {}

As discussed above, a wave is not located at one point in space. If the electron’s position is measured repeatedly, a spread in locations will be observed, implying an uncertainty in position ΔxΔx size 12{Δx} {}. To detect the position of the particle, we must interact with it, such as having it collide with a detector. In the collision, the particle will lose momentum. This change in momentum could be anywhere from close to zero to the total momentum of the particle, p=h/λp=h/λ size 12{p = h/λ} {}. It is not possible to tell how much momentum will be transferred to a detector, and so there is an uncertainty in momentum ΔpΔp size 12{Δp } {}, too. In fact, the uncertainty in momentum may be as large as the momentum itself, which in equation form means that

Δp≈hλ.Δp≈hλ. size 12{Δp approx { {h} over {λ} } } {}

The uncertainty in position can be reduced by using a shorter-wavelength electron, since Δx≈λΔx≈λ size 12{Δx approx λ} {}. But shortening the wavelength increases the uncertainty in momentum, since Δp≈h/λΔp≈h/λ size 12{Δp approx h/λ} {}. Conversely, the uncertainty in momentum can be reduced by using a longer-wavelength electron, but this increases the uncertainty in position. Mathematically, you can express this trade-off by multiplying the uncertainties. The wavelength cancels, leaving

ΔxΔp≈h.ΔxΔp≈h. size 12{ΔxΔp approx h} {}

So if one uncertainty is reduced, the other must increase so that their product is ≈h≈h size 12{ approx h} {}.

With the use of advanced mathematics, Heisenberg showed that the best that can be done in a simultaneous measurement of position and momentum is

ΔxΔp≥h4π.ΔxΔp≥h4π. size 12{ΔxΔp >= { {h} over {4π} } } {}

This is known as the Heisenberg uncertainty principle. It is impossible to measure position xx size 12{x} {} and momentum pp size 12{p} {} simultaneously with uncertainties ΔxΔx size 12{Δx} {} and ΔpΔp size 12{Δp} {} that multiply to be less than h/4πh/4π size 12{h/4π} {}. Neither uncertainty can be zero. Neither uncertainty can become small without the other becoming large. A small wavelength allows accurate position measurement, but it increases the momentum of the probe to the point that it further disturbs the momentum of a system being measured. For example, if an electron is scattered from an atom and has a wavelength small enough to detect the position of electrons in the atom, its momentum can knock the electrons from their orbits in a manner that loses information about their original motion. It is therefore impossible to follow an electron in its orbit around an atom. If you measure the electron’s position, you will find it in a definite location, but the atom will be disrupted. Repeated measurements on identical atoms will produce interesting probability distributions for electrons around the atom, but they will not produce motion information. The probability distributions are referred to as electron clouds or orbitals. The shapes of these orbitals are often shown in general chemistry texts and are discussed in The Wave Nature of Matter Causes Quantization.

Heisenberg Uncertainty Principle in Position and Momentum for an Atom

(a) If the position of an electron in an atom is measured to an accuracy of 0.0100 nm, what is the electron’s uncertainty in velocity? (b) If the electron has this velocity, what is its kinetic energy in eV?

Strategy

The uncertainty in position is the accuracy of the measurement, or Δx=0.0100nmΔx=0.0100nm size 12{Δx=0 “.” “0100”`”nm”} {}. Thus the smallest uncertainty in momentum ΔpΔp size 12{Δp} {} can be calculated using ΔxΔp≥h/4πΔxΔp≥h/4π size 12{ΔxΔp >= h”/4″π} {}. Once the uncertainty in momentum ΔpΔp size 12{Δp} {} is found, the uncertainty in velocity can be found from Δp=mΔvΔp=mΔv size 12{Δp=mΔv} {}.

Solution for (a)

Using the equals sign in the uncertainty principle to express the minimum uncertainty, we have

ΔxΔp=h4π.ΔxΔp=h4π. size 12{ΔxΔp = { {h} over {4π} } } {}

Solving for ΔpΔp size 12{Δp} {} and substituting known values gives

Δp=h4πΔx= 6.63× 10–34 J ⋅ s4π(1.00× 10–11 m)= 5.28 × 10–24 kg ⋅ m/s .Δp=h4πΔx= 6.63× 10–34 J ⋅ s4π(1.00× 10–11 m)= 5.28 × 10–24 kg ⋅ m/s . size 12{Δp = { {h} over {4π Δx} } = { {” 6″ “.” “63 ” times ” 10″ rSup { size 8{“–34″} } ” J ” cdot ” s”} over {4π ( 1 “.” “00” times ” 10″ rSup { size 8{“–11″} } ” m” ) } } =” 5″ “.” “28 ” times ” 10″ rSup { size 8{“–24″} } ” kg ” cdot ” m/s ” “.” } {}

Thus,

Δp= 5.28 × 10–24 kg ⋅ m/s =mΔv.Δp= 5.28 × 10–24 kg ⋅ m/s =mΔv. size 12{Δp =” 5″ “.” “28 ” times ” 10″ rSup { size 8{“–24″} } ” kg ” cdot ” m/s “= mΔv} {}

Solving for ΔvΔv size 12{Δv} {} and substituting the mass of an electron gives

Δv=Δpm=5.28 × 10–24 kg ⋅ m/s9.11 × 10–31 kg= 5.79 × 106 m/s.Δv=Δpm=5.28 × 10–24 kg ⋅ m/s9.11 × 10–31 kg= 5.79 × 106 m/s. size 12{Δv = { {Δp} over {m} } = { {5 “.” “28 ” times ” 10″ rSup { size 8{“–24″} } ” kg ” cdot ” m/s”} over {9 “.” “11 ” times ” 10″ rSup { size 8{“–31″} } ” kg”} } =” 5″ “.” “79 ” times ” 10″ rSup { size 8{6} } ” m/s” “.” } {}

Solution for (b)

Although large, this velocity is not highly relativistic, and so the electron’s kinetic energy is

KEe=12mv2=12(9.11 × 10–31 kg)(5.79 × 106 m/s)2=(1.53 × 10–17 J)(1 eV1.60 × 10–19 J)= 95.5 eV.KEe=12mv2=12(9.11 × 10–31 kg)(5.79 × 106 m/s)2=(1.53 × 10–17 J)(1 eV1.60 × 10–19 J)= 95.5 eV.alignl { stack {
size 12{“KE” size 8{e} = { {1} over {2} } ital “mv” rSup { size 8{2} } } {} #
=” 0″ “.” 5 ( 9 “.” “11 ” times ” 10″ rSup { size 8{“–31″} } ” kg” ) ( 5 “.” “79 ” times ” 10″ rSup { size 8{6} } ” m/s” ) rSup { size 8{2} } {} #
=” 1″ “.” “53 ” times ” 10″ rSup { size 8{“–17″} } ” J ” cdot { {“1eV”} over {1 “.” “60 ” times ” 10″ rSup { size 8{“–19″} } ” J”} } =” 95″ “.” “5 eV” “.” {}
} } {}

Discussion

Since atoms are roughly 0.1 nm in size, knowing the position of an electron to 0.0100 nm localizes it reasonably well inside the atom. This would be like being able to see details one-tenth the size of the atom. But the consequent uncertainty in velocity is large. You certainly could not follow it very well if its velocity is so uncertain. To get a further idea of how large the uncertainty in velocity is, we assumed the velocity of the electron was equal to its uncertainty and found this gave a kinetic energy of 95.5 eV. This is significantly greater than the typical energy difference between levels in atoms (see [link]), so that it is impossible to get a meaningful energy for the electron if we know its position even moderately well.

Why don’t we notice Heisenberg’s uncertainty principle in everyday life? The answer is that Planck’s constant is very small. Thus the lower limit in the uncertainty of measuring the position and momentum of large objects is negligible. We can detect sunlight reflected from Jupiter and follow the planet in its orbit around the Sun. The reflected sunlight alters the momentum of Jupiter and creates an uncertainty in its momentum, but this is totally negligible compared with Jupiter’s huge momentum. The correspondence principle tells us that the predictions of quantum mechanics become indistinguishable from classical physics for large objects, which is the case here.

# Heisenberg Uncertainty for Energy and Time

There is another form of Heisenberg’s uncertainty principle for simultaneous measurements of energy and time. In equation form,

ΔEΔt≥h4π,ΔEΔt≥h4π, size 12{ΔE Δt >= { {h} over {4π} } } {}

where ΔEΔE size 12{ΔE} {} is the uncertainty in energy and ΔtΔt size 12{Δt} {} is the uncertainty in time. This means that within a time interval ΔtΔt size 12{Δt} {}, it is not possible to measure energy precisely—there will be an uncertainty ΔEΔE size 12{ΔE} {} in the measurement. In order to measure energy more precisely (to make ΔEΔE size 12{ΔE} {} smaller), we must increase ΔtΔt size 12{Δt} {}. This time interval may be the amount of time we take to make the measurement, or it could be the amount of time a particular state exists, as in the next [link].

Heisenberg Uncertainty Principle for Energy and Time for an Atom

An atom in an excited state temporarily stores energy. If the lifetime of this excited state is measured to be 1.0×10−10s1.0×10−10s size 12{“10” rSup { size 8{ – “10”} } `s} {}, what is the minimum uncertainty in the energy of the state in eV?

Strategy

The minimum uncertainty in energy ΔEΔE size 12{ΔE} {} is found by using the equals sign in ΔEΔt≥h/4πΔEΔt≥h/4π size 12{ΔE Δt >= h”/4″π} {} and corresponds to a reasonable choice for the uncertainty in time. The largest the uncertainty in time can be is the full lifetime of the excited state, or Δt=1.0×10−10sΔt=1.0×10−10s size 12{Δt=”10″ rSup { size 8{ – “10”} } `s} {}.

Solution

Solving the uncertainty principle for ΔEΔE size 12{ΔE} {} and substituting known values gives

ΔE=h4πΔt=6.63 × 10–34 J ⋅ s4π(1.0×10–10 s)= 5.3 × 10–25 J.ΔE=h4πΔt=6.63 × 10–34 J ⋅ s4π(1.0×10–10 s)= 5.3 × 10–25 J. size 12{ΔE= { {h} over {4πΔt} } = { {6 “.” “63 ” times ” 10″ rSup { size 8{“–34″} } ” J ” cdot ” s”} over {4π ( “10” rSup { size 8{“–10″} } ” s” ) } } =” 5″ “.” “3 ” times ” 10″ rSup { size 8{“–25″} } ” J” “.” } {}

Now converting to eV yields

ΔE=(5.3× 10–25 J)(1 eV1.6 × 10–19 J)= 3.3 × 10–6 eV.ΔE=(5.3× 10–25 J)(1 eV1.6 × 10–19 J)= 3.3 × 10–6 eV. size 12{ΔE =” 5″ “.” “3 ” times ” 10″ rSup { size 8{“–25″} } ” J ” cdot { {“1 eV”} over {1 “.” “6 ” times ” 10″ rSup { size 8{“–19″} } ” J”} } =” 3″ “.” “3 ” times ” 10″ rSup { size 8{“–6″} } ” eV” “.” } {}

Discussion

The lifetime of 10−10s10−10s size 12{“10” rSup { size 8{ – “10”} } `s} {} is typical of excited states in atoms—on human time scales, they quickly emit their stored energy. An uncertainty in energy of only a few millionths of an eV results. This uncertainty is small compared with typical excitation energies in atoms, which are on the order of 1 eV. So here the uncertainty principle limits the accuracy with which we can measure the lifetime and energy of such states, but not very significantly.

There is another consequence of the uncertainty principle for energy and time. If energy is uncertain by ΔEΔE size 12{ΔE} {}, then conservation of energy can be violated by ΔEΔE size 12{ΔE} {} for a time ΔtΔt size 12{Δt} {}. Neither the physicist nor nature can tell that conservation of energy has been violated, if the violation is temporary and smaller than the uncertainty in energy. While this sounds innocuous enough, we shall see in later chapters that it allows the temporary creation of matter from nothing and has implications for how nature transmits forces over very small distances.

Finally, note that in the discussion of particles and waves, we have stated that individual measurements produce precise or particle-like results. A definite position is determined each time we observe an electron, for example. But repeated measurements produce a spread in values consistent with wave characteristics. The great theoretical physicist Richard Feynman (1918–1988) commented, “What there are, are particles.” When you observe enough of them, they distribute themselves as you would expect for a wave phenomenon. However, what there are as they travel we cannot tell because, when we do try to measure, we affect the traveling.

# Section Summary

• Matter is found to have the same interference characteristics as any other wave.
• There is now a probability distribution for the location of a particle rather than a definite position.
• Another consequence of the wave character of all particles is the Heisenberg uncertainty principle, which limits the precision with which certain physical quantities can be known simultaneously. For position and momentum, the uncertainty principle is ΔxΔp≥h4πΔxΔp≥h4π size 12{ΔxΔp >= { {h} over {4π} } } {}, where ΔxΔx size 12{Δx} {} is the uncertainty in position and ΔpΔp size 12{Δp} {} is the uncertainty in momentum.
• For energy and time, the uncertainty principle is ΔEΔt≥h4πΔEΔt≥h4π size 12{ΔEΔt >= { {h} over {4π} } } {} where ΔEΔE size 12{ΔE} {} is the uncertainty in energy and ΔtΔt size 12{Δt} {} is the uncertainty in time.
• These small limits are fundamentally important on the quantum-mechanical scale.

# Conceptual Questions

What is the Heisenberg uncertainty principle? Does it place limits on what can be known?

# Problems & Exercises

(a) If the position of an electron in a membrane is measured to an accuracy of 1.00 μm1.00 μm size 12{1 “.” “00 μm”} {}, what is the electron’s minimum uncertainty in velocity? (b) If the electron has this velocity, what is its kinetic energy in eV? (c) What are the implications of this energy, comparing it to typical molecular binding energies?

(a) 57.9 m/s

(b) 9.55×10−9 eV9.55×10−9 eV size 12{9 “.” “55” times “10” rSup { size 8{ – 9} } ” eV”} {}

(c) From [link], we see that typical molecular binding energies range from about 1eV to 10 eV, therefore the result in part (b) is approximately 9 orders of magnitude smaller than typical molecular binding energies.

(a) If the position of a chlorine ion in a membrane is measured to an accuracy of 1.00 μm1.00 μm size 12{1 “.” “00 μm”} {}, what is its minimum uncertainty in velocity, given its mass is 5.86×10−26 kg5.86×10−26 kg size 12{5 “.” “86” times “10” rSup { size 8{ – “26”} } ” kg”} {}? (b) If the ion has this velocity, what is its kinetic energy in eV, and how does this compare with typical molecular binding energies?

Suppose the velocity of an electron in an atom is known to an accuracy of 2.0×103 m/s2.0×103 m/s size 12{2 “.” 0 times “10” rSup { size 8{3} } ” m/s”} {} (reasonably accurate compared with orbital velocities). What is the electron’s minimum uncertainty in position, and how does this compare with the approximate 0.1-nm size of the atom?

29 nm,

290 times greater

The velocity of a proton in an accelerator is known to an accuracy of 0.250% of the speed of light. (This could be small compared with its velocity.) What is the smallest possible uncertainty in its position?

A relatively long-lived excited state of an atom has a lifetime of 3.00 ms. What is the minimum uncertainty in its energy?

1.10×10−13 eV1.10×10−13 eV size 12{1 “.” “10” times “10” rSup { size 8{ – “13”} } ” eV”} {}

(a) The lifetime of a highly unstable nucleus is 10−20 s10−20 s size 12{“10” rSup { size 8{ – “20”} } ” s”} {}. What is the smallest uncertainty in its decay energy? (b) Compare this with the rest energy of an electron.

The decay energy of a short-lived particle has an uncertainty of 1.0 MeV due to its short lifetime. What is the smallest lifetime it can have?

3.3×10−22 s3.3×10−22 s size 12{3 “.” 3 times “10” rSup { size 8{ – “22”} } ” s”} {}

The decay energy of a short-lived nuclear excited state has an uncertainty of 2.0 eV due to its short lifetime. What is the smallest lifetime it can have?

What is the approximate uncertainty in the mass of a muon, as determined from its decay lifetime?

2.66×10−46 kg2.66×10−46 kg size 12{2 “.” “66” times “10” rSup { size 8{ – “46”} } ” kg”} {}

Derive the approximate form of Heisenberg’s uncertainty principle for energy and time, ΔEΔt≈hΔEΔt≈h size 12{ΔE Δt approx h} {}, using the following arguments: Since the position of a particle is uncertain by Δx≈λΔx≈λ size 12{Δx approx λ} {}, where λλ size 12{λ} {} is the wavelength of the photon used to examine it, there is an uncertainty in the time the photon takes to traverse ΔxΔx size 12{Δx} {}. Furthermore, the photon has an energy related to its wavelength, and it can transfer some or all of this energy to the object being examined. Thus the uncertainty in the energy of the object is also related to λλ size 12{λ} {}. Find ΔtΔt size 12{Δt} {} and ΔEΔE size 12{ΔE} {}; then multiply them to give the approximate uncertainty principle.

## Glossary

Heisenberg’s uncertainty principle
a fundamental limit to the precision with which pairs of quantities (momentum and position, and energy and time) can be measured
uncertainty in energy
lack of precision or lack of knowledge of precise results in measurements of energy
uncertainty in time
lack of precision or lack of knowledge of precise results in measurements of time
uncertainty in momentum
lack of precision or lack of knowledge of precise results in measurements of momentum
uncertainty in position
lack of precision or lack of knowledge of precise results in measurements of position
probability distribution
the overall spatial distribution of probabilities to find a particle at a given location